Gas resonance system



oct. 29, 1957 Filed Jan. 26, 1955 L. E. NORTON GAS RESONANCE SYSTEM 3 Sheets-Sheet 1 asc af DC HMB Pil/755 COMP INVENTOR.

Oct. 29, 1957 L. E. NORTON LOWELL E. /Vmo/v 1 E. NORTON 2,811,644

GAS REsoNANcE SYSTEM 3 Sheets-Sheet 3 Oct. 29, 1957 Filed Jan. 26. 1955 @N 1b WHQL bv Q wl mmm@ n N wm mi@ United States Patent 2,811,644 GAS REsoNANCE SYSTEM Lowell E. Norton, Princeton, N. J., assgnor to Radio Corporation of America, a corporation of Delaware Application January 26, 1955, Serial No. 484,251 23 Claims. (Cl. Z50-36) This invention relates to microwave methods and apparatus in which a gas is excited to produce spectral lines having Doppler-reduced bandwidth.

The molecular absorption effects exhibited by various microwave absorptive resonant gases when subjected to microwave excitation have been employed in frequency control and gas analysis. For rigidity of control in frequency stabilization and for high resolution in microwave spectroscopy, the bandwidth of the detected absorption effects should be narrow with the natural width of the corresponding spectral line of the gas as the limit. Saturation-broadening of the spectral line is avoided by exciting the gas at sufficiently low power levels: collisionbroadening is avoided by employing gas at very low pressure: and Doppler-broadening is A.minimized by use of a gas cell having spatially periodic field to effect coherent absorption, over a very narrow frequency range, of gas molecules of all velocity classes.

A principal object of the present invention is to provide methods and systems which utilize vsuch narrow band, low intensity effect without serious degradation, by noise, of the precise frequency information contained in that effect.

In accordance with the present invention, the gas while confined at low pressure and subjected to a spatially periodic field is excited by oneo'f the microwave'frequencies existent upon modulation of a microwave frelquency by a lower frequency. The resulting microwave signal withdrawn from the confined body of gas is beat against one of the aforesaid microwave frequencies to produce a signal containing phase-information critically related to a molecular resonance frequency of the gas. This phase-sensitive signal is compared with a lowfrequency phase-reference signal, the phase relation between the signals being a measure of the difference between the exciting frequency and a molecular resonance frequency of the gas.

InA the methods and systems disclosed in the instant application the gas is subjected to a spatially periodic field only rather than4 to the combination of a spatially periodic field and a time-dependent field.

More particularly in accordance with specific aspects of the present invention, one of the aforesaid microwave -frequencies is impressed upon a gas-absorption cell having spatially periodic elds and no time dependent field to produce a microwave signal having phase-information which is critically dependent upon the molecular resonance absorption characteristic of the gas. By successive demodulations of this signal, rst by using one of the microwave frequencies as a beating signal and then by using the other intermediate frequency as a beating signal, there is produced a low-frequency signal containing the aforesaid phase-information. The phase relation of this low-frequency signal to a phase reference signal produced by mixing the `two intermediate frequencies is a measure of the difference between the gas-exciting microwave frequency and a molecular resonance frequency Patented Oct. 29, 1957 ice of the gas. Preferably and more particularly, the low'- frequency phase information signal and the low-frequency phase reference signal are utilized to produce a directcurrent control voltage of correspondingly variable polarity and amplitude which may be applied to control the frequency of the microwave carrier or to actuate the indicating or recording instrument of a microwave spectrograph.

Further in accordance with the invention, the frequency of the beating I. F. oscillations may be stabilized by a ysecond direct-current control signal produced by combining, as in a phase-comparator, the difference frequency of the intermediate frequency generators with the output of a stable low-frequency oscillator.

In some forms of the invention, the microwave'excita'- tion is continuously applied to the gas, whereas in other forms the microwave excitation is pulsed. In the latter, the microwave signal channel is gated so that the microwave frequency phase information signal is produced by molecular radiation continuing after termination of the individual exciting pulses.

Further in accordance with the invention, the lowfrequency phase information signal is amplified to high level in avoidance of need of high-gain, direct-current amplifiers with their inherent zero drift and instability.

The invention further resides in methods and systems having features hereinafter described and claimed.`

For a more detailed understanding of the invention and for illustration of the various embodiments thereof, reference is madeY to the accompanying drawings, in which:

Figure 1 diagrammatically illustrates a gas cell and associated means for producing spatially periodic fields therein;

Figure 1A is a graph illustrating voltages appliedto electrodes of 'the cellof Figure l;

Figure 2 is a plot of the transmission/frequency characteristic ofthe cell of Figure l; and

Figures 3A, 3B, 4A, and 4B are block diagrams sche, matically illustrating various systems utilizing the cell of Figure 1. v

The methods and systems herein specifically described involve use of a gas-absorption cell having spatially periodic fields and no time dependent field other than that of the exciting microwave frequency. Referring/to Figure l as exemplary of a cell of this type, cell 10 comprises a chamber 11 formed by a length of waveguide of circular or other suitable cross-section and which is sealed at opposite ends by windows 1'2 of mica 'or other insulating material transparent to microwave energy. The horns or tapered waveguides 13-14 at opposite ends of the chamber provide paths for transmission of microwave energy to or from the gas charnber. The direction of propagation of such energy in the cell is parallel to the axis of chamber 11.

The chamber 11 contains a gas such as ammonia exhibiting molecular resonance at microwave frequencies. Gases having such a property are, for example, ammonia, carbonyl sulfide, and the methyl halides. The gas in chamber 10 is at low pressure, for example, of .the order lof 10-5 millimeters of mercury.

current potentials of such magnitude that the electrostatic field strength in the region 'between the successive grids -alternates between two values E1E2 (Figures 1 and 1A). Specifically, the successive grids yare connected to points along a potential divider 16 supplied from a directcurrent source exemplified by battery 17 and r'heostat l 18. The alternate resistors R1 of the potential divider `are of equal value .of resistance. The other resistors R2 are of equal value different from the value of resistors R1.

Assuming by way of example that the gas is ammonia and designating an 4unperturbed spectral line frequency thereof as ya, the spectral line frequency for gas in the E1 field zones is v,=vl-BE12 and the yspectral line frequency for gas in the E2 vfield zones is v2=vn+BEz2- The Stark coefficient Bis appropriate for ammonia.

The proper microwave frequency for exciting the gas molecule ,in both the E1 :and E2 zones is:

the mean `of the two perturbed spectral line frequencies Thus far the effect of movement of the molecules has 'not been discussed. Because the absorbing gas molecules are at some temperature T, they have thermal energy kT) and move with random velocity through the grids 15vfrom one Stark field zone to another. Because of the low pressure of the gas, all molecules traversing the grids suffer a negligibly small number of collisions with other molecules. Furthermore, the transparency of the grids and the cell dimensions are sufficiently large to insure thatany molecular collisions with the grids and chamber wall contribute only negligibly to the total spectral line bandwidth.

Any molecule of any velocity class in traversing the grids 15 sees the perturbed spectral line frequencies v, v, in repeating sequence or spatial periodicity. Under this circumstance, the absorption of any molecule of any velocity class has, as referred to any arbitrary reference phase, a phase (el) while it is in an E1 field zone and another phase 2=-,) while it is in an E2 field zone. Therefore in traversing the series of grids 15, the absorption of a moving molecule of any velocity class undergoes a periodic phase-modulation which contains spectral line informationwhich may be utilized as is later described. The time derivative of this periodic phase-modulation, i. e., the corresponding frequency-modulation, also contains such spectral line information `and may be similarly utilized.

As now explained, the repetition frequency characteristic of the periodic phase-modulation depends upon the spacing between the grids and the particular velocity of the molecule passing through the grids. The spacing (S) between adjacent grids may be so selected that and hence the fundamental repetition frequency (f) of the molecular modulation is where c is the velocity of propagation in the cell of the excitation field of frequency vi.

With a sufficiently large number of grids 15, the spatial periodic stark field traversed by a molecule could be made sinusoidal and the only phase-modulation repetition-frequency would be the fundamental frequency f of Equation 4. Instead, and preferably, only a relatively Cit 4 few grids, `for example, 19 with `only 2 per period are used, and the resultant phase-modulation instead of being a single frequency is a plurality of discrete frcquencies:

where n is an integer, displaced from the excitation frequency v1 by if.

Consequently, a molecule moving with velocity v through the grid structure of the cell and subjected to an exciting microwave frequency u, ysees a Doppler-shifted frequency vp 11,-(1 :l:

where the minus or plus sign depends upon whether the molecular motion is the same as, or counter to, the ydirection of propagation of the excitation field of frequency y.. Because of the motion ofthe molecule, the Dopplerl shifted excitationfrequency is As discussed in connection with Equation 5, movement of the molecule through the spatial periodic Stark field results in discrete side frequencies displaced from the excitation frequency. Therefore molecular absorption for the Doppler-shifted excitation frequency occurs at discrete frequencies Furthermore, the fields associated with the firstorder upper sidebandfrequency (n={l) of the absorption 'also add coherently and in phase for all molecules moving .in the same direction as the direction of propagation of the exciting microwave field. Significantly, this discrete frequency-absorption occurs at 10) ."=0+; E12+E22 =a As shown by Equations 9 and l0, for halfwave spacing of the grids, the absorption of molecules of `all velocity classes, regardless of Doppler effect, is `coherent at the incident excitation frequency vi. All other discrete frequency-absorptions occur at frequencies which are functions of particular molecular velocities and so add incoherently in the frequency spectrum.

As shown in Figure 2, the frequency/transmission characteristic of gas confined in the cell of Figure l with halfwave` grid spacing has a very sharp absorption spike L, contributed to by all molecules, superposed on anormaiDoppler-broadened base line D. As exemplary of the ysharpness of the absorption spike, its observed width was' about 5 kilocycles at an impressed frequency of 25.7l5` kilomegacycles' for exciting the 7, 7 line of ammonia. In general, the Q of the spike L is of the order of 5X l06 or greater. This very narrow absorption spike contains the spectral line information of interest in microwave spectral analysis and in frequency control of microwave generators.

As n'ow` explained, such great sharpness is obtainable for other particular spacings of the grids 15. If the term a of Equation 8 is chosen to be 2( i. e., spacing S=7\), then the second order lower sideband frequencies of the absorption add coherently at excitation frequency vi for molecules of all velocity classes moving in direction contra to the'propagation of the microwave excitation field and the second order upper side frequencies of the absorption also add coherently at excitation or generally al, S 2 The systems shown in Figures 3A, 3B, 4A, 4B utilize the cell of Figure 1 and the relatively narrow bandwidth eiect of the sharp absorption spike L with substantially little degradation, by noise, of the precise spectral line frequency information.

Referring to Figure 3A, microwave output at frequency w from microwave generator 19 is applied to arm 4 of a magic tee T2. The generator 19 may be a klystron, magnetron or other suitable microwave oscillator: alternatively, it may be a lower frequency oscillator followed by frequency multipliers to provide microwave output at frequency w. The output at frequency w from arm 2 of magic tee T2 is supplied to arm'l of a second magic tee T1. A lower or intermediate frequency a, for example 30 megacycles, is supplied from oscillator 20 in -addition to the microwave carrier frequency w to diodesl 21, 21 in arms 3 and 4 of magic tee T1 Which is used as a balanced modulator to produce the microwave sideband frequencies (w-l-a), (w-a). The electrical length of these arms differs by an odd number of quarter-wavelengths at the carrier frequency w to permit parallel modulating excitation of diodes 21, 21. The output of modulator T1 is supplied to input horn 13 of gas cell 10 by output arm 2 of the modulator.

The frequencies w and a are so chosen that one of the mircowave frequencies is equal to the required excitation frequency ui. For example, and as a preferred operating adjustment, the carrier output w is largely suppressed in the balanced modulator and the upper sideband frequency is chosen to be equal to the required excitation frequency. The lower sideband frequency w-a is not at a frequency which excites molecular absorption and any residual of the suppressed carrier frequency (w) is also incorrect for molecular absorption excitation.

Having in mind that the carrier applied to modulator T1 is l1) e=E cos wt and that the modulating signal applied thereto is (12) e1=E1 cos at The only term of interest in the balanced modulator output for producing an exciting field in the gas cell is where mf is a modulator factor.

Thus, a molecule of any velocity class v traveling away from this eld will see The phase-modulation of the molecular absorption, which is due to the movement of the molecules atV thermal velocity through the spatial periodic Stark field, can be considered as negative field sources:

where ag has the dimensions of an absorption factor; I is the magnitude of the phase modulation component for repetition frequency --,vi (Equation 5) Assuming, for purposes of illustration, that the grid spacing is so chosen that a=1, then the only phase-modulation component of interest is the fundamental, and Equation l5 reduces to ag'mE where d, is the magnitude of the fundamental of the phase-modulation component.

By expanding Equation 16 and retaining only the first order side frequencies (the others being of no interest for a=1), Equation 15 further reduces:

and these molecules will see elds similar to those defined by Equations 14 and 15 except they will contain By expanding these and retaining only the first order sideband frequencies, an equation identical with Equation 17 will result.

In other words, the two first order phase-modulation components of the absorption add coherently and in phase. The transmission characteristics of the molecules of all velocity classes in the spatial periodic Stark eld of gas cell 10 therefore has, as shown in Figure 2, a veryy narrow bandwith at the frequency vi.

Because of the previously described transmission characteristics of gas cell 10, its output signal includes the term where :pg is a critical frequency dependent phase due to the anomalous behavior of the refractive index of the gas near molecular resonance.

The output of cell 10 is supplied through output horn 14 to arm 2 of a third magic tee T3 to whose arm 1 is supplied microwave energy of frequency w from arm 1 of magic tee T2. The magic tee T2 isolates the magic tees T1 and T3 from each other and also provides a transmission path, through its arms 3 and 4, from the microwave generator 19 to a load 22, such as an antenna system of a frequency-stabilized microwave transmitter.

In arms 3, 4 of magic tee T3, the fields at detectors 23, 23 have, because of knownproperties of the magic tee,

instead of a phase difference of 1r. "hese fields, incombinationwith T3. The output of stage 24 is applied to the intermediate frequency amplifier stage 26 and thence to the detector or mixer 27. The other input to mixer 27 is from a second lower or intermediate frequency `oscillator 28 operating 'at a frequency (owl-5) where the frequency difference is small, forrexample, in the range of from 30 to 2,000 cycles/second; Otherwise stated, the frequency of oscillator '28 is offset by a phase comparison servo from the fre- Yquenc'y of oscillator 20 by a relatively small and fixed amount. The output of filter 29 following the mixer 27 is (20) 8,: -agmmmlgeg co's (spray) where mg is a modulation factor.

The significant point is that the output of detector 27 is at a low sub-carrier frequency having the phase information pg of Equation l1, which phase information, as above stated, is critically dependent upon the absorption characteristics of the gas in cell 10. This output, after amplification by a high-gain low-frequency amplifier 30,*is impressed upon one input circuit of a phasecomparator 31 of any suitable type. Upon the other input circuit of phase-comparator 31 is impressed a phasereference signal of low frequency which is preferably derived as now described.

The outputs of the two intermediate oscillators 20 and 28 are applied to a mixer 32 to produce a difference frequency, normally having the value of which is amplilied by low-frequency amplifier 33 and `applied to one input circuit of a second phase-comparator 34. To the other input circuit of phase-comparator 34 is applied the output of a low-frequency oscillator 35 operating with good stability at the selected low-frequency which, as above stated, may be in the range of 30 to 2,000 cycles/ second.

The integrated output of phase-comparator 34 is a direct-'current signal whose polarity and amplitude vary in accordance with the sense and extent of deviation of the difference between the difference phases of oscillators 20 and `28K, andthe phase of oscillator 35. This signal, after amplification if necessary, is applied to a reactance tube 36 to control, in manner per se known, the phase of intermediate frequency oscillator 28.

The amplified difference frequency output of mixer f 32 is also applied through phase-shifter 37 to the second input circuit ofthe phase-comparator 31. This phase-referranceV signal as applied to phase-shifter 31 may be expressed as (21) eri-:Eg cosqaJm-ajo-Eg eos 5r pha'sefcrnpai'ator without degradation and under much ipv'ed siglitonoise Conditions.

When the microwave frequency i applied to cell 10 is equalhtofthensum (w-l-va) of the frequencies of oscillators 19 and 420and is equal to the requiredexcitation frequency of the gas, then 3:0 and e'=0. When, however, thefapplied `frequency departs from the required excitation frequeney in either direction, qb is positive or negative, depending Vupon the sense of the departure.

Because sin dagsin (-g), the signal voltage ae,

changes polarity for frequency deviations of opposite sense4 of departure. lThis direct-current signal containing the significant phase information is integrated, amplified by a low-gaindirect-current amplifier 42 when necessary, and utilized asa control voltage for controlling the frequency of the microwave oscillation generator 19. If generator 19 is a microwave oscillator, such as a klystron, the control voltage may be applied to a frequency-control electrode thereof. If it is a lower frequency oscillator followed by frequency multipliers, the control voltage may be applied to a reactance tube frequency-control for the oscillator. Both of these methods of frequency control are per se well known and need not be further described.

Since a high-gain low-frequency amplifier 30 may be used between mixer 27 and comparator 31, `it is not necessary to use a high-gain direct-current amplifier for the out'- put of comparator 31. Hence, the problems of zero drift and instability common to high-gain direct-current am plifiers are avoided. By way of example, the gain of the intermediate frequency amplifier 26 is of the order of 5000 and the gain of the low frequency amplifier 30 is of the order of 1000.

y The time-constant of integrator 39 following comparator 31 is made'appropriate for the low-frequency In practice, the effective bandwidth may be very narrowabout 0.05 wcycle-for a very stable source 19 as a crystalcontrolled oscillator followed by the necessary multiplier stages. A

The system shown in Figure 3B also provides for utilization of the small intensity, narrow bandwidth effect of the absorption spike L (Figure 2) without serious V,degradation, by noise, of the precise narrowrband information. This system is similar to that of Figure 3A except for addition f an Velectronic gate 40 and a pulse-generating unit 41. The latter produces electrical pulses, which as applied to gate 40, periodically open and close the transmission path from the modulating oscillator 20 to the balanced modulator T1, and which as applied to theintermediate frequency amplifier 26 periodically desensitizes and sensitizes it. The duration of the keying and blanking pulses may be of the order of one microsecond and the interval between pulses may be somewhat longer..

Designating the pulse repetition rate as p,v the effect of gating is to produce additional sideband frequencies spaced ip, 12p, i3p iup from the sideband frequency(w}a) and (tu-fa). For this reason, the pulse repetition frequency is chosen to be at least somewhat greater than the bandwidth of the absorption spike L of Figure 2.

The blanking pulses as applied to the intermediate frequency 26 make it inoperative during, and for a short time following, the application of excitation pulses to gas cell 10 so that in effect the signal received by `the mixer 27 is due to coherent emission continuing from the absorbing molecules after termination of their excitation. Further description of Figure 3B is unnecessary as the preceding description of Figure 3A is applicable thereto. y

The system shown in Figure 4A, except in respects specifically discussed below, is similar to that of Figure 3A whose description is generally applicable here. In the system of Figure 4A, `the single magic tee T4 replaces the two magic tees T 1, T3 of Figures 3A, 3B and serves both as a balanced modulator and as a balanced demodulator. In the system of Figure 4A, the,horn 14 of the gas-absorption cell 10 terminates in a reflector 45 k9 .so that the microwave excitation traverses the cell twice. The reflector 45 is so located for phasing of the incident and reflected excitation that the double traverse of the cell effects doubling of the signal field and quadrupling of the output signal power of the cell.

The microwave carrier w from the microwave generating means 19 is applied directly to arm 1 of the magic tee T4. The lower frequency output a of modulating oscillator 20 is applied to detectors 44, 44 in arms 3, 4 of the magic tee: so far as this output is concerned, the detectors operate in phase by virtue of the center-tap connection of winding 46 of input transformer 25 for the low-noise coupling stage 24.

Preferably, and as before described in connection with Figure 3A, the carrier and modulating frequency may be so chosen that the carrier being largely suppressed. Because of the ydifferential path length of arms 3, 4 the sideband outputs from the detectors 44, 44 to cell 10 are in phase. Because of the center-tap connection, the microwave excitation does not appear across the secondary winding 47 of 'input transformer 25 of stage 24.

differential in the length of its arms 3, 4 and the push-pull single-ended transformer 25, provide such overall phasing that the signal channel to detectors 44, 44 is effectively decoupled from the oscillator 20. Hence, forperfect adjustment, output from oscillator 20 does not enter the signal channel and I. F. amplifier, nor is signal channel power wasted by entering the output circuit of oscillator 20. The remainder of the system of Figure 4A is similar to that of Figure 3A and need not be further described.

In the system of Figure 4A, the microwave excitation and the microwave signal are simultaneously present in the combined modulator-demodulator T4. Since both are at the same frequency, this imposes severe requirements upon the design and balance of this unit.

Such requirement may be relaxed by modifying the system of Figure 4A to include provision for pulse excitation of the gas instead of continuous excitation. More specifically and as shown in Figure 4B, a gate 40 interposed in the path from oscillator 20 to the diodes 44 of the modulator-demodulator T4 is periodically operated by switching pulses from the keyer 41. Under pulsed excitation conditions, the magic tee T4 functions alternately, instead of simultaneously, as a balanced modulator supplying microwave excitation for cell l and as a balanced demodulator for the output signal of cell 10.

As in the system of Figure 3B, the lowest suitable yvalue of the pulse-repetition frequency is set by the width of the absorption spike L of Figure 2. The excitation pulses may, for example, be of one microsecond duration and the interval between pulses may be somewhat longer. Also, as in the system of Figure 3B, pulse output from keyer 41 is used to blank the amplifier 26 during each of the excitation pulses and for a short while thereafter so that the gas cell signal received by mixer 27 is in eect due to coherent emission continuing from the absorbing molecules after termination of the individual excitation pulses.

The system of Figure 4B is otherwise similar to that of Figure 3B and need not be further described.

, In all of the systemsv as above described, the directcurrent output of the phase-comparator 31 is utilized as a frequency-control voltage for the microwave generating unit 19. These systems may also be utilized in microwave spectroscopy for sharply resolving individual spectral lines of a gas or a mixture of gases. For such'latter purpose, the frequency of generating unit 19 is swept by manual adjustment or a sweep generator (not shown) over the absorption range to be investigated and the output of phase-comparator 31 is applied to a recorder or indicator 50 to show or plot the absorption of the gas over the scanned frequency range.

What is claimed is: i

l. A system for utilizing molecular resonance of a body of gas confined at low pressure which comprises, means for generating a microwave carrier frequency, means for amplitude-modulating said carrier frequency by a modulation signal to produce microwave sideband frequencies in addition to said carrier frequency, means for impressing one of the microwave frequencies upon said body of gas, means for subjecting" the excited gas to a spatially periodic field so as to produce a microwave output signal from said body of gas having phase information critically dependent upon the molecular resonance ofthe gas, means for beating the microwave output signal with one of said microwave frequencies to produce a low frequency signal containing said phase information, producing a low frequency phase-reference signal, and means for comparing the phase relation of said low frequency phase-reference signal and said low frequency signal resulting from said beating as a measure of the difference between a molecular resonance frequency of the gas and the microwave excitation frequency thereof. l

2. A system for utilizing molecular resonance of a body of gas confined at low pressure which comprises, means for generating a microwave carrier frequency, means for amplitude-modulating said carrier frequency by an intermediate frequency to produce microwave sideband frequencies in addition to said carrier frequency, means for impressing one of the microwave frequencies upon said body of gas, means for subjecting the excited gas to a spatially periodic field so to produce a microwave output signal from said body of gas having phase information critically dependent upon molecular resonance absorption of the gas, means for beating said microwave output signal with one of said microwave frequencies to produce an intermediate frequency signal, means for adding a low-frequency component to one ,of said signals whereby said component as appearing in said intermediate frequency signal contains said phase-information, means for detecting said low-frequency component of the intermed-iate frequency signal, means for producing a low-frequency phase-reference signal, and means for comparing the phase relation of said low-frequency phase-reference signal and the `detected low-frequency component as a measure of the difference between a molecular resonance frequency of the gas and the microwave excitation frequency thereof.

3. A system as in claim 2 in which the gas is continuously lexcited by a selected one of the microwave frequencies.

4. A system as in claim 2 in which the gas is periodically excited by a selected one of the microwave f-requencies and inwhich said low-frequency is periodically added only during non-excitation periods of the gas.

5. A system as in claim 2 in which means is provided for combining the low-frequency phase-reference signal and the detected low-frequency component to produce a direct-current control voltage of polarity and amplitude dependent upon the existing difference between the molecular resonance frequency of the gas and the microwave excitation frequency thereof.

6. A system as in claim 5 in which means is provided for applying the direct-current control signal to said 2, ei Leit-i 'generatigjsaid cai'n'er to stabilize the genmicrowave qu per A .A as inclim 5 in which the excitation frel y variedwover range and in which the directcurrentwfcntrel voltage is applied to an indicating or rcrding instrument,` l I 8A system as in claim 5 in which the `detected lowfreqnency component is amplified to high level in avoidance of netedufor high "amplification of the direct-current control signal. u n y V Y 9. A system for utilizingV molecular resonance of a gas confined `at low pressure which comprises, means for generating a I microwave carrier frequency, means for gener'ating a fir't termediate frequency, means for applying "said frequencie's-l to yankYamplitude-rriodulator to produce nl crowave `sidexbaiid,frequencies in addition to the microwave carrier. frequency, means for applying a bselectedy one of r'said microwave frequencies to excite the gs, yineans for" snbje'c`ti-ng` the excited gas to a spatially field so to produce a microwave signal having i "nformation ,critically dependent `upon molecularance bseijptibn of thergas, means for applying said cro ve `signal and one of said microwave frequencies t `a demodulator to produce an intermediate frequency al containing sa'idphase-information, means for generating a second intermediate frequency, means for apply- `said intermediate frequency signal and said second intermediate frequency to a mixer to produce a lowfrequency signal containing said phase-information, means forapplyin'gjsaid yfirst and second intermediate frequencies te a mixer `to produce Va low-frequency phase-reference signal, and means for applyingsaid low-frequency signals toa phase-comparator-to produce a direct-current control Voltage o f, polarityjand amplitude dependent upon the existing 'difference between a molecular resonance frequency of the gas and the microwave excitation frequency.

l0. Asystenmjas in c1ai`m 9 in which the low-frequency phase-reference Asignal is stabilized by generating a standard `signal of `the desired low-frequency, means is proforapplying said first and second intermediate frequencies to a second mixer to produce a frequency-difference signal, meansis provided for applying said standard IW-frequency vsignal and` said frequency-difference signal to `a second phase-.comparator to produce a freqnency-control voltage, and means is provided for apply- 'ing said frequency-control voltage to stabilize said second intermediate frequency.` Y

llsA system as in claim 9 in which the gas is continuously excited by a selected one of the microwave fre- Aqii'encies.

12. A system as in claim 9 in which the gas is periodically excited by a selected one of the microwave frequencies and in which the intermediate frequency signal 'is periodically applied tothe mixer and only during nonexcitation periods of the gas. y

13. A system'comprising a gas cell containing a molecularly resonant gas at lowpressure having a series of spaced electrodes therein, means connected to said electrodes to produce a spatially periodic field within said cell, `means for amplitude-modulating a carrier frequency by a modulation frequency to produce microwave sideband frequencies in' addition to said carrier frequency, means for impressing one of ,said microwave frequencies upon said body ofgas, means forrderiving an output signal `fromsaid body of gas having phase information critically dependent upon the Amolecular"resonant effect of said gas, means forbeating said microwave output signal withone of'saidmicrowave frequencies to produce a low frequency 'signal containing said` phase information, means for producinga low frequency 'phase-reference signal, and means forfcomparing the` phase .relationof `said low frequency phase-reference signal *and said low frequency signal re- `Sulling fromisaid beating'as ameasurelof Vthe difference betweenfa,mnlecularfresonance frequency of said gas and the microwave excitation frequency thereof.

Asysteni comprising a gas-absorption cellcontaining gas at low vpressure and having a series of spaced electrodes therein, a direct-current source connected t said electrodes to produce in said cell a spatially periodic field, a channel for supplying said cell with microwave excitation including an amplitude-modulator having in put circuits supplied with a microwave carrier frequency and an intermediate frequency to produce microwave sideband frequencies in addition to said microwave carrier frequency, said cell due to excitation of the gas while subjected to said spatially periodic field producing a microwave signal containing phase-information critically dependent upon molecular resonance-absorption of the gas,

a signal channel includingsaid cell and a demodulator having input ycircuits supplied with said cell signal and with one of said` microwave frequencies to produce an intermediate frequency signal containing said phaseinformation, means for producing `in said signal channel a low-frequency signal component having said phaseinformation of said intermediate-frequency signal, means for producing a low-frequency phase-reference signal, and means for comparing the phase relation of said lowfrequency phase-reference signal and said low-frequency phase-information signal as a measure of the difference between the excitation-frequency of said gas and a molecular `resonance frequency thereof. l

15. A system as in claim 14 in which a single magic tee serves both as said modulator and as said demodulator and in whichthe gas cell is connected at one end to an arm of `saidmagic tee, the other end of said cell being provided with a reflector.

16. A system as in claim l5 in which the gas is continuously excited, said magic tee simultaneously serving both as the modulator and as the demodulator.

17. A system as in claim l5 additionally including a periodically keyed gate in the intermediate frequency input circuit of the magic tee whereby the magic tee alternately serves as the modulator and the demodulator.

18.- A system as in claim 14 in which magic tees connected to opposite ends of the absorption cell respectively serve as the modulator means and the demodulator means and in `which a third magic tee supplies one of the microwave frequencies `to both of the other tccs while effectively decoupling `them for other frequencies.

19. A system as in claim 14 in which means is provided for deriving a 4direct-current control voltage from said phase comparison means and means is provided for applying the direct-current control voltage to frequencystabilize the means for generating the microwave carrier frequency.

20. A system as in claim 14 in which means isprovided to vary the microwave carrier frequency, means is provided for deriving a direct-current control voltage from said phase comparison means, and in which an indicating or recording instrument is connected for response to the direct-current control voltage.

2l. A system comprising means for generating a microwave carrier frequency and a first intermediate frequency, amplitude-modulator means having input circuits upon which said lfrequencies are impressed to produce microwavesideband frequencies in addition to said microwave carrier frequency, an absorption cell containing gas at low pressure and upon which one of said microwave frequencies is impressed, said cell having associated therewith means for producing therein spatially periodic fields at intervals corresponding with an integral number of half-wavelengths at the selectively impressed exciting frcquency, demodulator means upon which one of said microwave frequencies and the output of said absorption cell are impressed to produce an intermediate-frequency signal with phase-information critically dependent upon the gas absorption at and near molecular resonance, `means forV generating a second intermediate-frequency, a first mixer to which said second intermediate-frequencyand said intermediate-frequency signal are applied to produce a low-frequency signal containing said phase-information, a second mixer upon which said rst and second intermediate frequencies are impressed to produce a low-frequency phase-reference signal, and comparator means upon which said low-frequency phase-information signal and said lowfrequency phase-reference signal are applied to produce a direct-current control voltage of polarity and amplitude dependent upon the diierence between the exciting microwave frequency and a molecular resonance frequency of the gas.

22. A system as in claim 2l in which an electronic gate is in circuit between the modulator means and the means generating the rst intermediate frequency, in

which an intermediate frequency amplifier is in circuit between the demodulator means and the rst mixer, and in which a pulse-generator supplies keying pulses to said gate and blanking pulses to said amplier.

23. A system as in claim 21 in which a low-noise cascode coupling stage is in circuit between the demodulator means and the first mixer.

References Cited in the iile of this patent UNITED STATES PATENTS 2,524,290 Hershberger Oct. 3, 1950 

